Are asymmetric stretch Raman spectra by centrosymmetric molecules depolarized?: The 2 nu(3) overtone of CO2

作者：Chrysos M^*; Verzhbitskiy I A; Rachet F; Kouzov A P

来源：Journal of Chemical Physics, 2011, 134(4): 044318.

DOI：10.1063/1.3535599

Molecular vibrations that are not totally symmetrical give rise to depolarized lines [P. Atkins and J. de Paula, Atkins' Physical Chemistry (Oxford University Press, UK, 2006), p. 464]. But in the case of stretching vibrations in centrosymmetric molecules, the statement has so far not been conclusively verified. It is the purpose of this article to report a rigorous experimental and theoretical analysis of the 2 nu(3) band of CO2-the first overtone of the asymmetrical stretch vibration. The anisotropic spectrum was extracted and its spectral moment calculated from light-scattering measurements, taken at room temperature and for a wide range of CO2-gas densities. Evidence for a near-entirely depolarized Raman band is provided, with integrated depolarization ratio eta(int) = 6/7.16, closely approaching the upper bound eta(max) = 6/7. Agreement with theoretical predictions is found, on the basis of quality ab initio data for polarizability properties, provided that electro-optical and mechanical anharmonicity and intermode coupling effects between symmetric nu(1) and antisymmetric nu(3) stretching vibrations are incorporated.

• 出版日期2011-1-28