Nitrosobenzene as a hydrogen acceptor in rhodium catalysed dehydrogenation reactions of alcohols: synthesis of aldehydes and azoxybenzenes

作者：Annen Samuel P; Gruetzmacher Hansjoerg

来源：Dalton Transactions, 2012, 41(46): 14137-14145.

DOI：10.1039/c2dt31691a

Acids, esters and amides have to date been the only isolated products from the dehydrogenation of primary alcohols with [Rh(trop(2)N)(L)] (trop = 5-H-dibenzo[a,d]cyclohepten-5yl) type complexes. With the reported method the available product family is finally to aldehydes. Using nitrosobenzene as a hydrogen acceptor the aldehydes could be isolated in up to 96% yield with substrate to catalyst ratios of up to 1000. Nitrosobenzene was found to be reductively coupled to azoxybenzene under the reaction conditions. Several symmetrically substituted azoxybenzene derivatives could be isolated in generally high yields after 2 to 4 h reaction time using a low catalyst loading.

• 出版日期2012