A Self-Reducible and Alcohol-Soluble Copper-Based Metal-Organic Decomposition Ink for Printed Electronics

作者：Shin Dong Hun; Woo Seunghee; Yem Hyesuk; Cha Minjeong; Cho Sanghun; Kang Mingyu; Jeong Sooncheol; Kim Yoonhyun; Kang Kyungtae; Piao Yuanzhe^*

来源：ACS Applied Materials & Interfaces, 2014, 6(5): 3312-3319.

DOI：10.1021/am4036306

• conductive ink
• metal-organic decomposition ink
• alkanolamine
• copper formate

We report a novel method for the synthesis of a self-reducible (thermally reducible without a reducing atmosphere) and alcohol-soluble copper-based metal organic decomposition (MOD) ink for printed electronics. Alcohol-solvent-based conductive inks are necessary for commercial printing processes such as reverse offset printing. We selected copper(II) formate as a precursor and alkanolamine (2-amino-2-methyl-1-propanol) as a ligand to make an alcohol-solvent-based conductive ink and to assist in the reduction reaction of copper(II) formate. In addition, a co-complexing agent (octylamine) and a sintering helper (hexanoic acid) were introduced to improve the metallic copper film. The specific resistivity of copper-based MOD ink (Cuf-AMP-OH ink) after heat treatment at 350 degrees C is 9.46 mu Omega.cm, which is 5.5 times higher than the specific resistivity of bulk copper. A simple stamping transfer was conducted to demonstrate the potential of our ink for commercial printing processes.

• 出版日期2014-3-12