A Green Method for the Synthesis of Thiochromene Derivatives in Ionic Liquids

作者:Wang Xiang Shan*; Wu Jian Rong; Zhou Jie; Zhang Mei Mei
来源:Journal of Heterocyclic Chemistry, 2011, 48(5): 1056-1060.
DOI:10.1002/jhet.688

摘要

Controlling the pH value by changing the negative ion of ionic liquids, the same reactions of aromatic aldehyde, 2-(2,3-dihydrothiochromen-4-ylidene) malononitrile and malononitrile product unaromatized and aromatized 6H-benzo[c] thiochromene derivatives in high yields. The nice features of these procedures include mild reactions condition, simple operations, high yields, and environmentally benign.