A unique 1-amino-1-cyclopropane carboxylate cupric-cryptate hosting sodium

作者:Ghattas Wadih; Ricoux Remy; Korri Youssoufi Hafsa; Guillot Regis; Riviere Eric; Mahy Jean Pierre*
来源:Dalton Transactions, 2014, 43(21): 7708-7711.
DOI:10.1039/c4dt00500g

摘要

The first cluster containing acc was prepared via supramolecular self-assembly. This Cu(II) cluster traps Na+, as shown in the solid state by the crystal structure and in solution by ESI-MS. Further characterisations revealed a ferromagnetic intracluster exchange and an irreversible reduction with a rapid intracluster electron transfer.

  • 出版日期2014