科研之友
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摘要
Palladium-catalyzed oxidative arylations of terminal alkenes could be performed using sodium sulfinates at 60 degrees C in air. The procedure gave various aryl alkenes after the desulfonylation of sodium arylsulfinates in the presence of a palladium catalyst. For instance, the reaction of styrene with sodium phenylsulfinate afforded trans-1,2-diphenylethylene in 80% yield without the formation of other stereoisomers.
- 出版日期2013-12-2
