A high energy density Li-rich positive-electrode material with superior performances via a dual chelating agent co-precipitation route

作者:Hou, Peiyu; Xu, Long; Song, Jishun; Song, Dawei*; Shi, Xixi; Wang, Xiaoqing; Zhang, Lianqi
来源:Journal of Materials Chemistry A, 2015, 3(18): 9427-9431.
DOI:10.1039/c5ta01184a

摘要

A new Li-rich positive-electrode Li-1.13(Ni0.26Co0.09Mn0.52) O-2 is successfully achieved via a dual ammonia and oxalate chelating agent co-precipitation route for the first time, which delivers a high volumetric energy density of over 2100W h L-1, superior cycle life and stable high median-voltage. The dual or multiple chelating agent method gives a new insight towards high energy density for Li-rich materials with outstanding electrochemical performances for advanced lithium-ion batteries.