Disentangling disorder in the three-dimensional coordination network of {Ag-3[tris(2-pyridylmethyl)cyclotriguaiacylene](2)}(PF6)(3)

作者：Sumby CJ; Hardie MJ^*

来源：Crystal Growth & Design, 2005, 5(4): 1321-1324.

DOI：10.1021/cg050061e

The crystalline complex {Ag-3[Tris(2-pyridylmethyl)cyclotriguaiacylene](2)}(PF6)(3) has been synthesized and shown by X-ray crystallography to have a disordered three-dimensional cubic coordination network structure. The coordination network features a back-to-back stacking of the molecular host-type ligands into tetrahedral clusters, and the PF6- anions act as both intracavity guests and lattice-type guests. Disentangling the network disorder gives a 4-fold interpenetrating (10,3)-a net.

• 出版日期2005-8