Modeling and characterization of carbon nanotube agglomeration effect on electrical conductivity of carbon nanotube polymer composites

作者：Gong S; Zhu Z H^*; Li J; Meguid S A

来源：Journal of Applied Physics, 2014, 116(19): 194306.

DOI：10.1063/1.4902175

This paper investigated the effect of carbon nanotube (CNT) agglomeration on the electrical conductivity of CNT-polymer composites by experimental characterization and theoretical modeling. The present experimental results show that the acid treatment of CNTs has significantly alleviated the CNT agglomeration in CNT-polymer composites and improved the electrical conductivity of the composites compared with CNT-polymer composites made from the same pristine CNTs. The improvement by the acid treatment is further studied by a multiscale CNT percolation network model that considers the CNT agglomeration based on experimental observation. Numerical results are in good agreement with the experimental data. The smaller the size of CNT agglomerates is in the experiments, the closer the measured electrical conductivity of CNT-polymer composites is to its theoretical limit. The current study verifies that (i) the CNT agglomeration is the main cause that leads to a lower electrical conductivity of CNT-polymer composites than their theoretical limit, and (ii) the current multiscale percolation network model can quantitatively predict the electrical conductivity of CNT-polymer composites with CNT agglomeration. The comprehensiveness of the developed modeling approach enables an evaluation of results in conjunction with experimental data in future works.

• 出版日期2014-11-21