Diastereoselective allylation and crotylation of N-tert-butanesulfinyl imines with allylic alcohols

作者:Barros Olga Soares do Rego; Sirvent Juan Alberto; Foubelo Francisco*; Yus Miguel
来源:Chemical communications, 2014, 50(52): 6898-6901.
DOI:10.1039/c4cc02317j

摘要

The palladium-catalyzed allylation of N-tert-butanesulfinyl imines with allylic alcohols in the presence of InI as reducing reagent takes place with high diastereoselectivity in reasonable yields. The reaction with crotyl alcohol is totally regioselective, leading to the anti-diastereomer as the main reaction product.

  • 出版日期2014